Abstract The aim of this study is investigation of AC electrical properties for (PVA-PEG- Sb2O3) composite material at different frequencies which they ranged from 100Hz -6MHz. The PVA-PEG- Sb2O3 composite prepared using solution casting method. The experimental results have shown that the dielectric constant(ɛ) and dielectric loss (δ) decreases with increasing the frequency, it also appeared that ɛ and δ are increased with the increasing of antimony oxide (Sb2O3) content. The electrical conductivity (σ) increased with the increasing of frequency and decreased with the increasing of Sb2O3content in the PVA-PEG- Sb2O3composites.